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Position
| Band range |
Lorentzian |
Intensity |
Selected |
Fit range |
Origin |
Anharmonicity factors |
| μm |
cm⁻¹ |
Gaussian |
At 523 K |
Components |
K |
Y(0) |
c1 |
c2 |
c3 |
| ratio |
# | νpeak 523 K (cm⁻¹) |
cm⁻¹ |
10² cm⁻¹.T⁻¹ |
10⁴ cm⁻¹.T⁻² |
10⁶ cm⁻¹.T⁻³ |
|
|
|
1.0 |
4.8 |
1 |
708 |
300 ; 373 |
712.94 |
-0.89 |
|
|
|
|
1.0 |
4.8 |
1 |
708 |
300 ; 723 |
712.9 |
-0.87 |
|
|
|
|
1.0 |
4.8 |
1 |
708 |
423 ; 723 |
712.98 |
-0.89 |
|
|
|
|
0.4 |
2.16 |
3 |
742 |
300 ; 373 |
754.29 |
-1.69 |
|
|
|
|
0.4 |
2.16 |
3 |
742 |
300 ; 723 |
755.62 |
-2.34 |
|
|
|
|
0.4 |
2.16 |
3 |
742 |
423 ; 723 |
750.66 |
-1.53 |
|
|
|
|
|
1.0 |
12.51 |
1 |
837 |
423 ; 723 |
844.1 |
-1.23 |
|
|
|
|
|
1.0 |
1.71 |
1 |
1181 |
300 ; 373 |
1187.89 |
-1.04 |
|
|
|
|
1.0 |
1.71 |
1 |
1181 |
423 ; 723 |
1184.17 |
-0.52 |
|
|
|
|
|
0.7 |
2.84 |
1 |
1593 |
423 ; 723 |
1603.52 |
-2.02 |
|
|
|
|
|
1.0 |
11.05 |
1 |
3040 |
423 ; 673 |
3044.95 |
-0.88 |
|
|
|
|
1.0 |
11.05 |
1 |
3040 |
423 ; 723 |
3044.79 |
-0.85 |
|
|
|
|
0.9 |
2.15 |
2 |
2931 |
423 ; 673 |
2931.54 |
-0.02 |
|
|
|
|
0.9 |
2.15 |
2 |
2931 |
423 ; 723 |
2931.73 |
-0.06 |
|
|
|
|
0.0 |
0.36 |
3 |
2888 |
423 ; 673 |
2887.33 |
0.22 |
|
|
|
|
0.0 |
0.36 |
3 |
2888 |
423 ; 723 |
2888.25 |
0.04 |
|
|
|
|
0.0 |
0.23 |
4 |
2859 |
423 ; 673 |
2865.22 |
-1.22 |
|
|
|
|
0.0 |
0.23 |
4 |
2859 |
423 ; 723 |
2866.12 |
-1.39 |
|
|
|
|
0.7 |
0.5 |
5 |
2831 |
423 ; 673 |
2831.44 |
0.04 |
|
|
|
|
0.7 |
0.5 |
5 |
2831 |
423 ; 723 |
2831.7 |
-0.01 |
|
|
FWHM
| Band range |
Lorentzian |
Intensity |
Selected |
Fit range |
Origin |
Anharmonicity factors |
| μm |
cm⁻¹ |
Gaussian |
At 523 K |
Components |
K |
Y(0) |
c1 |
c2 |
c3 |
| ratio |
# | νpeak 523 K (cm⁻¹) |
cm⁻¹ |
10² cm⁻¹.T⁻¹ |
10⁴ cm⁻¹.T⁻² |
10⁶ cm⁻¹.T⁻³ |
|
|
|
1.0 |
4.8 |
1 |
708 |
300 ; 373 |
1.41 |
0.1 |
|
|
|
|
1.0 |
4.8 |
1 |
708 |
300 ; 723 |
-0.07 |
0.61 |
|
|
|
|
1.0 |
4.8 |
1 |
708 |
423 ; 723 |
1.1 |
0.42 |
|
|
|
|
0.4 |
2.16 |
3 |
742 |
300 ; 373 |
3.99 |
0.44 |
|
|
|
|
0.4 |
2.16 |
3 |
742 |
300 ; 723 |
3.39 |
0.9 |
|
|
|
|
0.4 |
2.16 |
3 |
742 |
423 ; 723 |
9.16 |
-0.04 |
|
|
|
|
|
1.0 |
12.51 |
1 |
837 |
423 ; 723 |
5.0 |
0.52 |
|
|
|
|
|
1.0 |
1.71 |
1 |
1181 |
300 ; 373 |
0.14 |
0.76 |
|
|
|
|
1.0 |
1.71 |
1 |
1181 |
423 ; 723 |
0.93 |
0.83 |
|
|
|
|
|
0.7 |
2.84 |
1 |
1593 |
423 ; 723 |
10.89 |
1.86 |
|
|
|
|
|
1.0 |
11.05 |
1 |
3040 |
423 ; 673 |
25.1 |
0.45 |
|
|
|
|
1.0 |
11.05 |
1 |
3040 |
423 ; 723 |
23.35 |
0.8 |
|
|
|
|
0.9 |
2.15 |
2 |
2931 |
423 ; 673 |
35.93 |
-0.8 |
|
|
|
|
0.9 |
2.15 |
2 |
2931 |
423 ; 723 |
34.97 |
-0.61 |
|
|
|
|
0.0 |
0.36 |
3 |
2888 |
423 ; 673 |
14.09 |
1.41 |
|
|
|
|
0.0 |
0.36 |
3 |
2888 |
423 ; 723 |
11.05 |
2.01 |
|
|
|
|
0.0 |
0.23 |
4 |
2859 |
423 ; 673 |
9.38 |
3.02 |
|
|
|
|
0.0 |
0.23 |
4 |
2859 |
423 ; 723 |
13.31 |
2.24 |
|
|
|
|
0.7 |
0.5 |
5 |
2831 |
423 ; 673 |
17.54 |
-0.05 |
|
|
|
|
0.7 |
0.5 |
5 |
2831 |
423 ; 723 |
14.78 |
0.5 |
|
|
Intensity
| Components |
Intensity (cm⁻¹) |
| νpeak 523 K (cm⁻¹) |
300.0 K |
323.0 K |
373.0 K |
423.0 K |
473.0 K |
523.0 K |
573.0 K |
623.0 K |
673.0 K |
723.0 K |
| 708.4 |
3.23 |
3.26 |
3.32 |
4.34 |
4.6 |
4.8 |
5.03 |
5.31 |
5.61 |
5.93 |
| 722.8 |
0.63 |
0.64 |
0.67 |
0.85 |
0.94 |
1.03 |
1.11 |
1.16 |
1.14 |
1.01 |
| 742.5 |
1.94 |
1.93 |
1.92 |
2.05 |
2.06 |
2.16 |
2.28 |
2.42 |
2.54 |
2.62 |
| 752.2 |
0.51 |
0.53 |
0.55 |
0.38 |
0.42 |
0.43 |
0.44 |
0.44 |
0.43 |
0.4 |
| 837.7 |
|
|
|
11.52 |
12.15 |
12.51 |
12.89 |
13.31 |
13.78 |
14.23 |
| 827.7 |
|
|
|
1.97 |
1.95 |
1.91 |
1.8 |
1.58 |
1.22 |
0.81 |
| 820.2 |
|
|
|
0.48 |
0.47 |
0.5 |
0.57 |
0.68 |
0.84 |
0.84 |
| 1181.5 |
1.44 |
1.46 |
1.5 |
1.71 |
1.7 |
1.71 |
1.74 |
1.79 |
1.84 |
1.88 |
| 1593.0 |
|
|
|
2.83 |
2.88 |
2.84 |
2.77 |
2.65 |
2.49 |
2.47 |
| 1660.3 |
|
|
|
0.07 |
0.08 |
0.08 |
0.1 |
0.11 |
0.11 |
0.12 |
| 1637.8 |
|
|
|
0.65 |
0.58 |
0.48 |
0.37 |
0.28 |
0.28 |
0.33 |
| 1543.1 |
|
|
|
0.06 |
0.05 |
0.04 |
0.02 |
0.01 |
0.0 |
0.02 |
| 3040.4 |
|
|
|
10.43 |
10.86 |
11.05 |
11.68 |
11.68 |
12.03 |
13.0 |
| 2931.3 |
|
|
|
2.29 |
2.22 |
2.15 |
2.06 |
2.07 |
1.88 |
1.88 |
| 2888.7 |
|
|
|
0.39 |
0.37 |
0.36 |
0.37 |
0.36 |
0.35 |
0.38 |
| 2859.3 |
|
|
|
0.21 |
0.21 |
0.23 |
0.2 |
0.22 |
0.21 |
0.23 |
| 2831.5 |
|
|
|
0.59 |
0.54 |
0.5 |
0.45 |
0.43 |
0.35 |
0.36 |
| Total intensity |
7.77 |
7.82 |
7.96 |
40.81 |
42.07 |
42.75 |
43.87 |
44.48 |
45.1 |
46.53 |